In an exclusive interview with ABC News anchor David Muir, Ukraine President Volodymyr Zelenskyy stressed that the United States and NATO should establish a no-fly zone over his country to stop Russian missiles from hitting civilian targets like a university dormitory and a pediatric clinic.

"Mr. President, as you know, the president [Joe Biden] and NATO have said no to this no-fly zone because of concerns this could trigger a much wider ... conflict, a much bigger war than what we're seeing already because there would have to be a willingness to shoot Russian planes outta the sky. Do you understand that concern?" Muir asked.

Zelenskyy, speaking to Muir from the Presidential Office in Kyiv, said that while Biden and NATO have refused to impose a no-fly zone, Russian missiles continue to target civilians, adding that he believes Russian missiles should be shot out of the sky.

"You have to preserve lives. There ... were simply kids there with tumors," Zelenskyy said of the missile strike on the pediatric clinic. "And in the university, there were ordinary students. I'm sure that the brave American soldiers who would be shooting it down knowing that it is flying towards the students, I'm sure that they had no doubt in doing so."

The White House indicated on Monday that it was considering a ban on Russian oil even without the support of its European allies, an official with the National Security Council told ABC News.

Europe relies much more on Russian oil and gas than the United States does and would likely see much higher prices if such a significant chunk of their energy imports were suddenly cut off.

If the United States banned Russian oil imports without Europe doing the same, the impact on Russia would be much smaller than if the U.S. and Europe worked in concert. Russia exported 1% of its oil exports to the United States in 2020.

Moving forward without Europe would also be a departure from Biden’s approach of working in lockstep with Europe on sanctions against Russia.

Bloomberg reported Sunday night that the Biden administration was weighing this move.

-ABC News' Ben Gittleson

In an exclusive interview Monday with ABC News anchor David Muir, Ukraine President Volodymyr Zelenskyy said the path to peace is "more difficult than simply acknowledging" another ultimatum from Russian President Vladimir Putin.

Zelenskyy spoke with Muir from the Presidential Office in Kyiv and said he will stay in his country for the duration of the war.

"When the Kremlin says these three conditions to end the war … that you must give up on joining NATO, recognize Crimea as part of Russia and recognize the independence of those two separatist regions in the east … you say it’s a nonstarter, not willing to [accept] those three conditions right now?" Muir asked.

Zelenskyy responded, "It is more difficult than simply acknowledging them ... this is another ultimatum and we are not prepared for ultimatums."

He went on, "But we have the possible solution resolution for these three items, key items, what needs to be done is for President Putin to start talking. Start the dialogue instead of living in the information bubble without oxygen. I think that’s where he is. He is in this bubble. He’s getting this information and you don’t know how realistic that information is that he’s getting."

President Joe Biden is scheduled to hold a secure video teleconference Monday morning with leaders of France, Germany and the United Kingdom to discuss the latest developments regarding Russia and Ukraine, according to the White House.

Biden is expected to be in the White House Situation Room when he participates in a teleconference with French President Emmanuel Macron, German Chancellor Olaf Scholz and British Prime Minister Boris Johnson, according to the White House.

The teleconference will be closed to the press and will occur after Biden received his daily intelligence briefing, the White House said.

-ABC News' Ben Gittleson

U.S. Secretary of State Antony Blinken crossed the border into Ukraine Saturday after meeting with Ukrainian Foreign Minister Dmytro Kuleba at the Korczowa Border Crossing Point.

"The entire world stand with Ukraine," Blinken said, and Kuleba added that he hopes Ukrainians will see this as a "clear manifestation that we have friends who literally stand by us."

Blinken said the sanctions imposed so far against Russia are "producing very, very concrete results" and that the pressure will "grow" until this "war of choice is brought to an end."

When asked directly about helping Kuleba with more firepower, Blinken said, "the support for Ukraine not only has been unprecedented, not only is going to continue, it's going to increase."

Kuleba said Ukraine "appreciates" sanctions that have been announced in the last week, but that more economic and political pressure and "necessary weapons," would "save many lives in Ukraine... many sufferings will be avoided."

Kuleba also said that they are “satisfied" with already arranged supplies of anti-tank weapons and ammunition, but that “it’s no secret” they still want fighter jets and air defense systems.

He also thanked the U.S. for sending stingers, and said they were used on Saturday.

"Just today we shot down three Russian attack aircrafts, which were bombing our cities with the use of stingers but we need -- so to say -- big air defense systems to ensure the safety of our skies. If we lose the skies, there will be much, much more blood on the ground,"Kuleba said.

In response to questions about NATO’s refusal to impose a no-fly zone over Ukraine, Kuleba said it’s a "sign of weakness," but stayed optimistic that they will change their minds.

"The time will come," he said.

-ABC News' Conor Finnegan and Justin Gomez